What is the material of ASTM A335 P9 boiler tube

Jul 10, 2025

1. Core material characteristics
‌ASTM A335 P9‌ is a chromium-molybdenum high-temperature alloy seamless steel pipe. Its chemical composition is designed with chromium (Cr) and molybdenum (Mo) as the core strengthening elements. The specific composition is as follows:

Element Content Range Functions
Cr 8.00%-9.50% High temperature oxidation resistance (forming dense Cr₂O₃ film)
Mo 0.90%-1.10% Improved creep resistance and high temperature strength
C ≤0.15% Balanced strength and weldability
Mn 0.30%-0.60% Resilience Enhancement
Si 0.25%-1.00% Deoxidation and high temperature stability

A335 P9 pipe

2. Performance advantages
‌High temperature performance‌:
‌Upper limit of applicable temperature‌:‌ 650℃‌ (long-term service temperature ≤ 600℃), creep resistance is better than ordinary alloy steel;
Tensile strength ≥ 415 MPa at 600℃, yield strength ≥ 205 MPa.
‌Corrosion resistance‌:
High chromium content effectively resists hydrogen sulfide corrosion‌ and high-temperature cyclohexane acid corrosion‌ (typical environment of petrochemical cracking furnace);
Oxidation resistance meets the working conditions of 550~630℃ boiler reheater.

 

3. Comparison with other alloy steels

Parameter A335 P9 A335 P91
Core Ingredients 9Cr-1Mo 9Cr-1Mo-V-Nb
Strengthening Mechanism Solid solution strengthening Dispersion strengthening (V/Nb carbides)
Allowable stress ≤ 600℃≈80 MPa ≥110 MPa at 600°C (increased by 37.5%)
Applications Medium and high pressure boiler superheater, petrochemical furnace tube Main steam pipeline of supercritical unit

 

A335 P9 pipe